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Synthesis of s ‐triazine polyetherols from bis(methoxymethyl)melamine and oxiranes
Author(s) -
Lubczak Jacek
Publication year - 1997
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19971017)66:3<423::aid-app2>3.0.co;2-r
Subject(s) - melamine , triazine , melamine resin , polymer chemistry , solvent , ethylene glycol , chemistry , organic chemistry , coating
Polyetherols containing s ‐triazine rings can be obtained in reactions of oxiranes with melamine derivatives. A report on the attempt to replace pentakis(methoxymethyl)melamine with bis(methoxymethyl)melamine in the synthesis is presented. The replacement simplified the procedure by eliminating the stage of transetherification with ethylene glycol. The oxirane addition was carried out without a solvent. The course of the reaction was studied and some properties of the resulting polyetherols determined. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 423–433, 1997