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A study on blends of liquid crystalline copolyesters with polycarbonate. III. Mechanical properties of compatibilized blends
Author(s) -
Wei KungHwa,
Ho JiaChong
Publication year - 1997
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19970321)63:12<1527::aid-app3>3.0.co;2-q
Subject(s) - materials science , polycarbonate , ultimate tensile strength , differential scanning calorimetry , compatibilization , composite material , izod impact strength test , transesterification , polymer blend , thermal stability , polymer , polymer chemistry , copolymer , chemical engineering , organic chemistry , catalysis , physics , chemistry , engineering , thermodynamics
Blends of liquid crystalline poly(oxybenzoate‐ co ‐oxynaphthalate) (Vectra A950) and polycarbonate (PC) were prepared by adding a compatibilizer to the two polymers in a melt‐blending process. The compatibilizer was based on controlled transesterification between synthesized poly(oxybenzoate‐ co ‐terephthalate) (40/60) and PC. The compatibilizer exhibited birefringence, and its thermal property was analyzed by differential scanning calorimetry. The maximum increase in tensile modulus and tensile strength of these compatibilized Vectra blends were 24% and 54%, respectively, as compared with those of binary Vectra blend without compatibilizer resulting from an injection‐molding process. The tensile properties of the compatibilized Vectra blends decreased once the concentration of the compatibilizer exceeded 2 phr. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 63: 1527–1533, 1997