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Study of cryostructuration of polymer systems. XII. Poly(vinyl alcohol) cryogels: Influence of low‐molecular electrolytes
Author(s) -
Lozinsky V. I.,
Domotenko L. V.,
Zubov A. L.,
Simenel I. A.
Publication year - 1996
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19960912)61:11<1991::aid-app13>3.0.co;2-2
Subject(s) - vinyl alcohol , swelling , electrolyte , hofmeister series , chaotropic agent , salt (chemistry) , polymer chemistry , polymer , chemistry , salting out , materials science , aqueous solution , organic chemistry , composite material , electrode
The influence of the presence of low‐molecular electrolytes in initial solutions of poly(vinyl alcohol) (PVA) on the results of cryotropic gelation of the polymer (gelation caused by the freezing thawing) and on the swelling characteristics of PVA cryogels prepared in a salt‐free medium were studied. The reinforcing ability of the electrolytes with respect to the gel strength for both alkaline element cations and simple low‐molecular anions has been shown to be in agreement with the positions of these ions in corresponding lyotropic (Hofmeister) series. Namely, the ions (chaotropic ones), which are capable to interfere the H‐bonding, disturbed somewhat the cryotropic gel‐formation of PVA and facilitated the marked additional swelling of cryogels preliminary prepared in pure water medium, whereas the ions (antichaotropic ones), which are capable to promote the H‐bonding, caused the formation of reinforced cryogels and resulted in the shrinking of cryogels prepared without salt additives. More pronounced effects were observed for anions as compared with cations. Some anomalous swelling behavior of PVA cryogel in Cs + ‐containing solutions was supposed to be associated with the formation of weak chelates. In addition to antichaotropic inorganic salts like NaF, rather high salting‐out effects in respect to PVA were exhibited by wellsoluble amino acid salts: glycine zwitter‐ions, lysine monochlorohydrate, and monosodium aspartate. © 1996 John Wiley & Sons, Inc.