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Digital model of macromolecule crosslinking
Author(s) -
Shyichuk A. V.
Publication year - 1996
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19960906)61:10<1703::aid-app10>3.0.co;2-3
Subject(s) - macromolecule , gel point , polymer science , polymer , polymer chemistry , materials science , molecular mass , fraction (chemistry) , thermodynamics , chemistry , composite material , chromatography , organic chemistry , physics , biochemistry , enzyme
A digital model of the MWD changes under polymer crosslinking is described in detail. The model yields full MWD, its average molecular weights and other average parameters, and the gel point and gel fraction vs. the crosslinks number. The model is verified to be in essential agreement with the crosslinking theory predictions. © 1996 John Wiley & Sons, Inc.