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High reactivity of hexafluoro acetone toward criegee intermediates in the gas‐phase ozonolysis of simple alkenes
Author(s) -
Horie Osamu,
Schäfer Christian,
Moortgat Geert K.
Publication year - 1999
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/(sici)1097-4601(1999)31:4<261::aid-kin3>3.0.co;2-z
Subject(s) - ozonolysis , chemistry , acetone , gas phase , reactivity (psychology) , organic chemistry , medicinal chemistry , photochemistry , computational chemistry , medicine , alternative medicine , pathology
Hexafluoro acetone CF 3 COCF 3 has been shown to react rapidly with the CH 2 OO, CH 3 CHOO, and (CH 3 ) 2 COO intermediates that are formed in the ozonolysis of C 2 H 4 , trans ‐2‐C 4 H 8 , and 2,3‐dimethyl‐2‐butene, respectively, and to form products tentatively assigned to the corresponding secondary ozonides. Relative rate method applied to the C 2 H 4 ozonolysis has indicated that CF 3 COCF 3 reacts ∼13 times faster than CH 3 CHO. © 1999 John Wiley & Sons, Inc., Int J Chem Kinet 31: 261–269, 1999