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Products of the gas‐phase photooxidation reactions of 1‐propanol with OH radicals
Author(s) -
Azad K.,
Andino J. M.
Publication year - 1999
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/(sici)1097-4601(1999)31:11<810::aid-jck8>3.0.co;2-w
Subject(s) - chemistry , propionaldehyde , radical , acetaldehyde , propanol , gas phase , mass spectrometry , gas chromatography , hydroxyl radical , photochemistry , acrolein , organic chemistry , chromatography , methanol , ethanol , catalysis
An experimental investigation of the hydroxyl radical initiated gas‐phase photooxidation of 1‐propanol in the presence of NO was carried out in a reaction chamber using gas chromatography mass spectrometry. The products identified in the OH radical reactions of 1‐propanol were propionaldehyde and acetaldehyde, with corresponding formation yields of 0.719 ± 0.058 and 0.184 ± 0.030, respectively. Errors represent ±2σ. The experimental product yields were compared to predictions made using chemical mechanisms. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 810–818, 1999