Kinetics of the gas‐phase reaction of Cl atoms with CF 2 ClCFClH at 263–313 K | Zendy

Mauer T. | Zendy; Wallington T. J. | Zendy; Barnes I. | Zendy; Becker K. H. | Zendy

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Kinetics of the gas‐phase reaction of Cl atoms with CF 2 ClCFClH at 263–313 K

Author(s) -

Mauer T.,

Wallington T. J.,

Barnes I.,

Becker K. H.

Publication year - 1999

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/(sici)1097-4601(1999)31:11<785::aid-jck4>3.0.co;2-p

Subject(s) - chemistry , gas phase , kinetics , molecule , phase (matter) , measure (data warehouse) , thermodynamics , analytical chemistry (journal) , organic chemistry , physics , quantum mechanics , database , computer science

Relative rate techniques were used to measure k (Cl + CF 2 ClCFClH) = (1.4 −1.0 +4.2 ) × 10 −11 exp[−(2360 ± 400)/T] cm 3 molecule −1 s −1 ; k (Cl + CF 2 ClCFClH) = 5.1 × 10 −15 cm 3 molecule −1 s −1 at 298 K. This result is discussed with respect to the available data. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 785–788, 1999

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