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Kinetics of the gas‐phase reaction of Cl atoms with CF 2 ClCFClH at 263–313 K
Author(s) -
Mauer T.,
Wallington T. J.,
Barnes I.,
Becker K. H.
Publication year - 1999
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/(sici)1097-4601(1999)31:11<785::aid-jck4>3.0.co;2-p
Subject(s) - chemistry , gas phase , kinetics , molecule , phase (matter) , measure (data warehouse) , thermodynamics , analytical chemistry (journal) , organic chemistry , physics , quantum mechanics , database , computer science
Abstract Relative rate techniques were used to measure k (Cl + CF 2 ClCFClH) = (1.4 −1.0 +4.2 ) × 10 −11 exp[−(2360 ± 400)/T] cm 3 molecule −1 s −1 ; k (Cl + CF 2 ClCFClH) = 5.1 × 10 −15 cm 3 molecule −1 s −1 at 298 K. This result is discussed with respect to the available data. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 785–788, 1999