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1 H and 13 C NMR characterization of poly[3‐(6‐methoxyhexyl)‐2,2′‐bithiophene]
Author(s) -
Iarossi D.,
Mucci A.,
Schenetti L.,
Costa Bizzarri P.,
Della Casa C.,
Lanzi M.
Publication year - 1999
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/(sici)1097-458x(199903)37:3<182::aid-mrc434>3.0.co;2-q
Subject(s) - chemistry , triad (sociology) , regioselectivity , nuclear magnetic resonance spectroscopy , fluorine 19 nmr , characterization (materials science) , two dimensional nuclear magnetic resonance spectroscopy , ring (chemistry) , carbon 13 nmr , stereochemistry , proton nmr , organic chemistry , catalysis , nanotechnology , materials science , psychology , psychoanalysis
A full 1 H and 1 C NMR study throughthe use of one‐ and two‐dimensional techniques(HMQC, HMBC, TOCSY and NOE‐difference spectroscopy)was carried out onpoly[3‐(6‐methoxyhexyl)‐2,2′‐bithiophene]. Inter‐ring correlations detected in the HMBC spectra proved to be a valuable tool in the assignment of regiochemistry. NMR data can be interpreted on the basis of a four‐triad model. Copyright © 1999 John Wiley & Sons, Ltd.