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Structure Elucidation of the Photooxygenation Products of 1,2‐Dihydronaphthalenes
Author(s) -
Tóth Gábor,
Linker Torsten,
Rebien Frank
Publication year - 1997
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/(sici)1097-458x(199706)35:6<367::aid-omr95>3.0.co;2-v
Subject(s) - photooxygenation , chemistry , cycloaddition , stereochemistry , ene reaction , organic chemistry , carbon 13 nmr , proton nmr , singlet oxygen , catalysis , oxygen
Photooxygenation of 1,2‐dihydronaphthalenes resulted in diendoperoxides and hydroperoxides via [4+2] cycloaddition and ene reactions, respectively. The relative configuration and stereochemistry of the products were elucidated by various 1 H and 13 C NMR methods. © 1997 John Wiley & Sons, Ltd.