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‘Time‐Dependent’ Resonance Raman Theory
Author(s) -
Myers Anne B.
Publication year - 1997
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/(sici)1097-4555(199706)28:6<389::aid-jrs128>3.0.co;2-m
Subject(s) - raman spectroscopy , resonance (particle physics) , raman scattering , chromophore , time domain , chemistry , coherent anti stokes raman spectroscopy , photon , interpretation (philosophy) , x ray raman scattering , molecular physics , nuclear magnetic resonance , atomic physics , physics , optics , photochemistry , computer science , computer vision , programming language
This review summarizes theoretical formulations of resonance Raman scattering that express the steady‐state spectrum in terms of time‐dependent quantities. Time‐domain expressions for the Raman or direct one‐photon absorption (electronic or vibrational) lineshape are compared and contrasted with time‐dependent formulations for the resonance Raman intensity. Time‐domain expressions that properly describe the total spontaneous emission of a chromophore interacting with a bath are also discussed. A final section addresses a few aspects of the interpretation and practical application of these theories to real experimental data. © 1997 John Wiley & Sons, Ltd.