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K x‐ray emission spectra of Ni in nickel(II) Schiff base complexes
Author(s) -
Shigemi Akio,
Tochio Tatsunori,
Ishizuka Takashi,
Shigeoka Nobuyuki,
Ito Kunio,
Vlaicu AurelMihai,
Ito Yoshiaki,
Mukoyama Takeshi,
Gohshi Yohichi
Publication year - 1999
Publication title -
x‐ray spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
eISSN - 1097-4539
pISSN - 0049-8246
DOI - 10.1002/(sici)1097-4539(199911/12)28:6<478::aid-xrs382>3.0.co;2-5
Subject(s) - nickel , schiff base , spectral line , x ray , crystallography , emission spectrum , chemistry , crystal structure , magnetic susceptibility , crystal (programming language) , materials science , physics , optics , organic chemistry , programming language , computer science , astronomy
K x‐ray emission spectra of Ni were measured in bis( N ‐isopropylsalicylideneaminato)nickel(II) and bis( N ‐isobutylsalicylideneaminato)nickel(II) with different types of coordination, planar or pseudo‐tetrahedral, using a double‐crystal x‐ray spectrometer. The relationship between the magnetic susceptibility and the energy spectra of the K β 2,5 and K β ′ emission lines was investigated for these compounds. The electronic structures of the compounds were also studied by the use of the molecular orbital method. Copyright © 1999 John Wiley & Sons, Ltd.