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TOAC, a nitroxide spin‐labeled, achiral C α ‐tetrasubstituted α‐amino acid, is an excellent tool in material science and biochemistry
Author(s) -
Toniolo Claudio,
Crisma Marco,
Formaggio Fernando
Publication year - 1998
Publication title -
peptide science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.556
H-Index - 125
eISSN - 1097-0282
pISSN - 0006-3525
DOI - 10.1002/(sici)1097-0282(1998)47:2<153::aid-bip4>3.0.co;2-t
Subject(s) - nitroxide mediated radical polymerization , chemistry , electron paramagnetic resonance , amino acid , inducer , spin label , helix (gastropod) , site directed spin labeling , fluorescence , stereochemistry , amino acid residue , combinatorial chemistry , nuclear magnetic resonance , organic chemistry , biochemistry , peptide sequence , polymer , copolymer , radical polymerization , ecology , physics , quantum mechanics , membrane , biology , snail , gene
The 2,2,6,6‐tetramethylpiperidine‐1‐oxyl‐4‐amino‐4‐carboxylic acid is a nitroxide spin‐labeled, achiral C α ‐tetrasubstituted α‐amino acid that has recently been shown to be an effective β‐turn and 3 10 /α‐helix inducer in peptides and an excellent and relatively rigid electron spin resonance probe and fluorescence quencher. © 1998 John Wiley & Sons, Inc. Biopoly 47: 153–158, 1998