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The use of static mass spectrometry to determine the combined stable isotopic composition of small samples of atmospheric methane
Author(s) -
Jackson Sarah M.,
Morgan Geraint H.,
Morse Andrew D.,
Butterworth Anna L.,
Pillinger Colin T.
Publication year - 1999
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(19990715)13:13<1329::aid-rcm648>3.0.co;2-p
Subject(s) - chemistry , methane , mass spectrometry , isotope analysis , stable isotope ratio , analytical chemistry (journal) , composition (language) , natural abundance , trace gas , isotope , gas composition , environmental chemistry , atmospheric methane , mineralogy , chromatography , geology , thermodynamics , linguistics , oceanography , physics , philosophy , organic chemistry , quantum mechanics
Global budgets of atmospheric trace gases are increasingly being constrained by means of stable isotope measurements. Published analytical techniques for studying the parallel stable isotopic composition of methane (δ 13 C and δD) require prohibitively large quantities of methane for analysis, making them unsuitable for studies where sample size is small, e.g. soil methane fluxes. A highly sensitive static mass spectrometer has been developed which uniquely uses CH 4 as the analyte. The method requires only 8 ng of CH 4 for analysis (<10 mL ambient air), making replicated measurements of the isotopic composition of CH 4 in small samples feasible for the first time. This paper provides the first detailed description of the instrumentation and the analytical technique. The technique has been used to analyse small samples of air collected in Snowdonia over 21 months. The combined stable isotopic composition (δ 17 M) ranged from 29.5 to 35.5‰, with an average value of 32.2‰, and was strongly correlated with wind direction (p <0.01, r 2 = 0.71). Copyright © 1999 John Wiley & Sons, Ltd.