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A fragmentation study of some diethylindium cyclic imides
Author(s) -
Grafova Irina A.,
Traldi Pietro,
Strelko Vladimir V.,
Battiston Giovanni A.,
Rossetto Gilberto
Publication year - 1998
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(19981015)12:19<1351::aid-rcm306>3.0.co;2-u
Subject(s) - chemistry , fragmentation (computing) , pyrrolidine , piperidine , electron ionization , mass spectrometry , azetidine , kinetic energy , ionization , ion , gas phase , computational chemistry , analytical chemistry (journal) , organic chemistry , chromatography , physics , quantum mechanics , computer science , operating system
The electron ionization mass spectrometric behaviour of a series of diethylindium complexes with imino ligands derived from piperidine, pyrrolidine, azetidine, methylaziridine and dicyclopropylamine were investigated. These data have been compared with those from mass‐analysed ion kinetic energy spectrometry. Fragmentation patterns of the complexes in question give information relevant to their gas‐phase behaviour as precursors for III–V semiconducting materials via metal‐organic chemical vapour deposition. A comparison with analogous derivatives of dimethylindium is also discussed. © 1998 John Wiley & Sons, Ltd.