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Self‐assembly of N,O‐bis(trimethylsilyl)amino acids to peptides mediated by o ‐phenylene phosphorochloridate identified by fast atom bombardment mass spectrometry
Author(s) -
Fu Hua,
Li ZhaoLong,
Zhao YuFen,
Xiao HongZhan,
Wang JingZun
Publication year - 1998
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(19980131)12:2<94::aid-rcm114>3.0.co;2-7
Subject(s) - chemistry , fast atom bombardment , trimethylsilyl , fragmentation (computing) , mass spectrometry , phenylene , amino acid , peptide , ion , stereochemistry , medicinal chemistry , organic chemistry , chromatography , biochemistry , polymer , computer science , operating system
The self assembly of N,O‐bis(trimethylsilyl)amino acids to form peptides, mediated by o ‐phenylene phosphorochloridate, was investigated by positive ion fast atom bombardment and B/E linked‐scan techniques without isolation and purification prior to analysis. The expected results were confirmed by considering the fragmentation regularity of peptides. © 1998 John Wiley & Sons, Ltd.