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Chlorine‐containing thermal decomposition products from plastics pigments studied by pyrolysis ‐ mass spectrometry and pyrolysis ‐ gas chromatography/mass spectrometry
Author(s) -
Blazsó Marianne
Publication year - 1998
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(19980115)12:1<1::aid-rcm106>3.0.co;2-n
Subject(s) - chemistry , mass spectrometry , pyrolysis , pyrolysis–gas chromatography–mass spectrometry , thermal decomposition , gas chromatography , decomposition , chlorine , analytical chemistry (journal) , gas chromatography–mass spectrometry , chromatography , organic chemistry
Analytical pyrolysis methods were applied to the study of evolution of chlorinated thermal decomposition products from organic plastics pigments. The identification of the organic volatile compounds was performed by fast pyrolysis‐gas chromatography/mass spectrometry. In addition, temperature programmed pyrolysis‐mass spectrometry was conducted on samples introduced via the direct inlet probe. Monitoring appropriate molecular ion intensities allowed the formation of the organic products and that of hydrogen halides to be followed as a function of probe temperature programmed to increase at a constant rate. © 1998 John Wiley & Sons, Ltd.