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Mobility of anions within anion–neutral complexes. Cross ring hydride ion migration upon collisional activation of the para ‐formylbenzyloxy anion
Author(s) -
Dua Suresh,
Bowie John H.
Publication year - 1997
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(199712)11:18<1959::aid-rcm104>3.0.co;2-b
Subject(s) - chemistry , ion , hydride , ring (chemistry) , nucleophile , nucleophilic substitution , medicinal chemistry , catalysis , organic chemistry , hydrogen
The p ‐formylbenzyloxy anion, on collisional activation, undergoes the following cross‐ring hydride induced nucleophilic substitution reaction: p OHC‐C 6 H 4 ‐CH 2 O − →[( p ‐OHC‐C 6 H 4 ‐CHO)H − ]→ − OH 2 C‐C 6 H 4 ‐ p ‐CHO. © 1997 John Wiley & Sons, Ltd.