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Ion/Molecule Equilibria in Fullerene Vapours, Electron Affinities of Higher Fullerenes and Some Fluoroderivatives
Author(s) -
Sidorov Lev N.,
Boltalina Olga V.,
Borshchevsky Audrey Ya.
Publication year - 1997
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/(sici)1097-0231(199704)11:6<662::aid-rcm836>3.0.co;2-3
Subject(s) - fullerene , chemistry , molecule , vapours , ion , electron affinity (data page) , fullerene chemistry , computational chemistry , chemical physics , affinities , corannulene , organic chemistry , stereochemistry , neuroscience , biology
Abstract New accurate data for the series of 21 higher fullerenes including the first electron affinity ( EA ) measurements for [72]‐ and [74]‐fullerenes were obtained by the recently developed ion/molecule equilibria method. The regularity of the EA change in the larger fullerene series is analyzed and correlation with the available data on the electronic structure of fullerene molecules and anions is discussed. © 1997 John Wiley & Sons, Ltd.