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Addition‐fragmentation of 5‐bromopenta‐1,3‐diene in free radical polymerization of methyl methacrylate
Author(s) -
Reghunadhan Nair C. P.
Publication year - 1998
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/(sici)1097-0126(199808)46:4<313::aid-pi30>3.0.co;2-y
Subject(s) - chain transfer , radical polymerization , polymer chemistry , macromonomer , methyl methacrylate , polymerization , copolymer , diene , fragmentation (computing) , cobalt mediated radical polymerization , chemistry , reversible addition−fragmentation chain transfer polymerization , polymer , organic chemistry , natural rubber , computer science , operating system
5‐Bromopenta‐1,3‐diene (BPD) was examined as an addition‐fragmentation chain transfer agent (AFCTA) in the free radical polymerization of methyl methacrylate (MMA). Studies of the kinetics of polymerization in the presence of this compound showed it to be a very effective chain transfer agent and that retardation was not significant, implying efficient reinitiation by the expelled Br radical. Analysis of the resulting polymers showed that the intermediate radical formed by the addition of the propagating radical to the C 1 carbon of BPD underwent exclusive fragmentation. However, addition on the C 4 carbon, with a relative probability of 0·6, led to its copolymerization with MMA. Kinetic studies showed BPD to be a better chain‐end functionalization agent than its 5‐ t ‐butyl thio derivative for deriving pentadiene‐functional macromonomer. © 1998 SCI.