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Equilibrium surface segregation of silver to the low‐index surfaces of a copper single crystal
Author(s) -
Wang J. Y.,
du Plessis J.,
Terblans J. J.,
van Wyk G. N.
Publication year - 1999
Publication title -
surface and interface analysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.52
H-Index - 90
eISSN - 1096-9918
pISSN - 0142-2421
DOI - 10.1002/(sici)1096-9918(199908)28:1<73::aid-sia621>3.0.co;2-e
Subject(s) - copper , surface (topology) , single crystal , yield (engineering) , crystallography , crystal (programming language) , materials science , chemistry , metallurgy , geometry , mathematics , computer science , programming language
The equilibrium surface segregation of Ag to the low‐index surfaces of Cu single crystals is presented. It is found that the close‐packed surface of the (111) orientation allows a high interaction parameter resulting in a discontinuous transition in the surface concentration against temperature, as well as a step in the segregation kinetics. In contrast, the rougher surfaces of the (110) and (100) orientations yield smaller interaction parameter values and a smooth transition in surface coverage against temperature is observed. Copyright © 1999 John Wiley & Sons, Ltd.

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