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Distribution of organic carbon in bed sediments of Manoa Stream, Oahu, Hawaii
Author(s) -
Sutherland Ross A.
Publication year - 1999
Publication title -
earth surface processes and landforms
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.294
H-Index - 127
eISSN - 1096-9837
pISSN - 0197-9337
DOI - 10.1002/(sici)1096-9837(199907)24:7<571::aid-esp975>3.0.co;2-f
Subject(s) - sediment , total organic carbon , silt , drainage basin , grain size , hydrology (agriculture) , geology , fluvial , soil science , environmental science , mineralogy , environmental chemistry , structural basin , geomorphology , chemistry , geotechnical engineering , cartography , geography
Organic carbon (OC) associated with fluvial bed sediment plays an important role in biotic and abiotic processes operating within drainage basins. Increasingly, there is a need to characterize storage and spatial distributions of OC in aquatic sediments, particularly under‐sampled areas like tropical streams. The objectives of this study were to examine in detail the variation of OC concentration with bed sediment grain size, to characterize the influence of grain size variation on relative OC mass storage, and to compare weighted OC values to those in other aquatic sediments worldwide. The study area selected was a third‐order dendritic drainage basin developed in a basaltic complex. Bed sediments along a 6 km section of Manoa Stream were systematically sampled every 50 m for a total of 113 sample site locations. Sediments were partitioned into six size fractions (< 2·0 mm) and OC was determined by dry combustion. Data indicate that the OC concentration increases with decreasing grain size, with the greatest values in the < 0·063 mm (silt + clay) fraction, approximately 4·6 times greater than the very coarse sand fraction (1·00–2·00 mm). Robust smoothing techniques illustrated a general decrease in OC concentration downstream for the size fractions < 0·25 mm. Bed sediments were dominated by size fractions coarser than 0·5 mm (80 per cent of the total distribution) and only about 2 per cent in the fractions less than 0·13 mm. Combining information on OC concentration per size fraction and the mass contribution of each fraction to the whole sample, it was observed that fractions coarser than 0·5 mm had eight to 12 times the storage of OC per kilogram of bed sediments than the fractions finer than 0·13 mm. Weighted OC values for Manoa Stream were on average 6·7 g‐OC kg−1, and these were similar to those reported in the literature for a variety of sediments in aquatic environments, both freshwater and marine. These data provide important information on the relative mass storage of OC in bed sediments and their longitudinal patterns in a tropical fluvial environment. Copyright © 1999 John Wiley & Sons, Ltd.