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Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands
Author(s) -
Giobbio Ginevra,
Montrieul Anaïs,
Lohier JeanFrançois,
Costa Rubén D.,
Gaillard Sylvain
Publication year - 2025
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202500030
Abstract Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N‐Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis‐pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.