Premium
2D/3D Heterojunction Engineering for Hole Transport Layer‐Free Carbon‐Based Perovskite Solar Cells
Author(s) -
Li Lingcong,
Lai Yinlong,
Rao Huashang,
Cai Weizi,
Zhong Xinhua,
Guo Huishi,
Pan Zhenxiao
Publication year - 2025
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202402549
Subject(s) - heterojunction , passivation , perovskite (structure) , materials science , layer (electronics) , optoelectronics , carbon fibers , nanotechnology , electrode , chemical engineering , chemistry , composite number , composite material , engineering
Abstract Hole transport layer (HTL)‐free carbon‐based perovskite solar cells (C‐PSCs) own outstanding potential for commercial applications due to their attractive advantages of low cost and superior stability. However, the abundant defects and mismatched energy levels at the interface of the perovskite/carbon electrode severely limit the device efficiency and stability. Constructing a 2D layer on the surface of 3D perovskite films to form 2D/3D heterojunctions has been demonstrated to be an effective method of passivating surface defects and optimizing the energy level alignment in almost all kinds of PSCs. Due to the unique structure of HTL‐free C‐PSCs, 2D/3D heterojunctions play especially important roles. This review article summarizes the reports of 2D/3D perovskite heterojunctions in HTL‐free C‐PSCs. It describes the contributions of 2D/3D heterojunctions in terms of their roles in defect passivation, energy level optimization, and stability improvement. Finally, challenges and prospects of 2D/3D heterojunction for further development of HTL‐free C‐PSCs are highlighted.
Empowering knowledge with every search
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom