Cover Feature: Asymmetric Total Synthesis of (+)‐ and (−)‐Myrioneurinol Employing a “Resolutive” Late‐Stage Barton‐McCombie Deoxygenation

Almost 50 years after the first report of the so‐called Barton–McCombie deoxygenation reaction, a resolutive version of this transformation has been developed by using a chiral chlorothionoformate‐type reagent. The utility of this method was demonstrated by its late‐stage application to access both enantiomers of myrioneurinol, a complex tetracyclic alkaloid. More information can be found in the Research Article by P. A. Peixoto# and co‐workers (DOI: 10.1002/chem.202500267).