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ƞ 6 ‐Fluoranthene Complexes from the Reactions of Osmacyclopentadienes with Alkynes
Author(s) -
Zhao Yue,
Sun Yue,
Fu Bingjie,
Wang Yarong,
Zhou Yan,
Li Yang,
Liu Di,
Bai Wei
Publication year - 2025
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202500536
Abstract Osmacyclopentadiene complexes were obtained from the reactions between OsCl 2 (PPh 3 ) 3 and 1,8‐dialkynyl naphthalene compounds. These complexes exhibited paramagnetism as they adopted triplet ground states. Reactions of osmacyclopentadienes with alkynes were investigated, which produced novel η 6 ‐fluoranthene complexes, showing their potential in organometallic synthesis.