Outside Front Cover: A Bench‐stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application (Angew. Chem. Int. Ed. 24/2025)

The air‐ and water‐stable Ni(0) complex [Ni(PFPh 2 ) 4 ] is obtained via a unique in‐situ reduction and fluorination mechanism from [Ni(MeCN) 4 ](BF 4 ) 2 and Ph 2 P(═O)─PPh 2 , incorporating typically unstable fluorophosphine ligands. In their Research Article ( e202506271 ), Schirin Hanf et al. demonstrated its utility as a robust Ni(0) source, and showed its superior catalytic activity in coupling reactions compared to the conventional [Ni(COD) 2 ].