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p‐Type TiO 2 Nanotubes: Quantum Confinement and Pt Single Atom Decoration Enable High Selectivity Photocatalytic Nitrate Reduction to Ammonia
Author(s) -
Jung Hayoon,
Kim Hyesung,
Will Johannes,
Spiecker Erdmann,
Schmuki Patrik
Publication year - 2025
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202415865
Subject(s) - photocatalysis , selectivity , ammonia , nitrate , reduction (mathematics) , photochemistry , materials science , atom (system on chip) , chemistry , nanotechnology , inorganic chemistry , chemical engineering , catalysis , organic chemistry , geometry , mathematics , computer science , engineering , embedded system
Abstract We synthesize p‐type TiO 2 nanotubes that allow band‐gap adjustment by quantum confinement. These tubes therefore enable reductive photocatalytic reactions that are not thermodynamically possible on classic titania photocatalysts. Here, we demonstrate the direct photocatalytic nitrate reduction to ammonia without any need of hole scavengers. The quantum confinement effect (and thus the thermodynamic driving force) can be controlled by the thickness of the nanotube walls. Notably, the use of Pt single atoms as cocatalysts decorated on the TiO 2 nanotubes additionally offers a superior ammonia production and a remarkable enhanced selectivity compared to Pt nanoparticles. Overall, the work not only highlights the potential of size‐controlled modifications of electronic properties in extending the utility of a most classical photocatalyst but also exemplifies its use in technologically relevant reactions.