Study on Effects of Ni/Al2O3Catalysts Added with Mo on Durability Improvement in Steam Reforming Reactions
Author(s) -
Jong Min Won,
G. Park,
JinWoo Lee,
Sung Chang Hong
Publication year - 2016
Publication title -
korean chemical engineering research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.168
H-Index - 9
eISSN - 2233-9558
pISSN - 0304-128X
DOI - 10.9713/kcer.2016.54.4.560
Subject(s) - catalysis , steam reforming , x ray photoelectron spectroscopy , carbon fibers , materials science , nickel , chemical engineering , inorganic chemistry , nuclear chemistry , metallurgy , chemistry , hydrogen production , composite number , organic chemistry , composite material , engineering
− In this study, we characterized steam reforming reactions and surface of Ni/Al 2 O 3 catalysts. Ni-Mo based catalysts were prepared by loading Mo as the co-catalyst and reaction activities of the Ni-Mo based catalysts were compared with those of Ni-based catalysts. Through the H 2 -TPR and XPS analysis it was confirmed that this characteristic efficiency. O 2 -TPO analysis was performed to examine the deposition characteristics, bonding structures and evaporation characteristics of carbon deposited on the surface of catalysts after long run experiments were performed for steam reforming reactions. As the results, it was found that durability was improved in Ni-Mo based catalysts inhibiting formation of graphitic carbon species which reduced reaction activities of the catalysts by strongly interacting with Ni in the steam reforming reaction.
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