Effect of Colloidal Silica on the Photochromic Properties of Hard Coating Films Prepared by Sol-Gel Method
Author(s) -
Yong Tak Shin,
Min Ji Lee,
Kyung Sook Cho,
Ki Chang Song
Publication year - 2011
Publication title -
korean chemical engineering research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.168
H-Index - 9
eISSN - 2233-9558
pISSN - 0304-128X
DOI - 10.9713/kcer.2011.49.5.535
Subject(s) - photochromism , coating , materials science , sol gel , colloid , colloidal silica , chemical engineering , nanotechnology , engineering
Organic-inorganic hybrid coating solutions were prepared starting from colloidal silica, lanthanum nitrate and γ-glycidoxypropyl trimethoxysilane by the sol-gel method. Also, spiropyran-doped hard coating solutions were pre- pared by mixing the spiropyran solution, obtained after dissolving spiropyran dye into tetrahydrofuran solvent, with the organic-inorgnic hybrid coating solutions. The spiropyran-doped hard coating solutions were applied as a thin layer to polycarbonate sheets, and their photochromic properties were investigated. The effect of amount of colloidal silica added into the coating solutions was investigated on the photochromic properties of coating films. Both decoloration rate and pencil hardness of the coating films were increased with increasing the amounts of colloidal silica.
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