A Study on Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle by Heat Recovery
Author(s) -
JiHyun Cho,
Tae-Beom Seo
Publication year - 2017
Publication title -
journal of the korean solar energy society
Language(s) - English
Resource type - Journals
eISSN - 2508-3562
pISSN - 1598-6411
DOI - 10.7836/kses.2017.37.2.013
Subject(s) - hydrogen production , hydrogen , thermochemical cycle , thermal decomposition , materials science , decomposition , thermal , chemical engineering , nuclear engineering , water splitting , thermodynamics , chemistry , catalysis , biochemistry , physics , organic chemistry , photocatalysis , engineering
Two-step water splitting thermochemical cycle with CeO2/ZrO2 foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of CeO2/ZrO2 foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of CeO2/ZrO2 and NiFe2O4/ZrO2 foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to 200°C and, when the N2/steam is preheated to 200°C in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this.
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