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A simple, rapid, selective and sensitive spectrophotometric method for the determination of platinum(IV) was developed, based on the color reaction between platinum(IV) and 2nitrobenzaldehydethiocarbohydrazone (2-NBATCH) in the pH range 6.4-7.8. The red colored species have been developed after heating the reaction mixture in boiling water bath for 5 min and it was extracted into chloroform. The complex has an absorption maximum at 440 nm. A 20 fold of excess of reagent was required for complete complex formation. Beer’s law was obeyed for platinum(IV) concentration in the range of 4-12 µg mL-1 and the optimum concentration range was 6-12 µg mL-1 of platinum(IV) as evaluated by Ringbom’s plot. The molar absorptivity and Sandell’s sensitivity were 1.03  104 L mol-1 cm-1 and 0.0189 µg cm-2, respectively. The effect of pH, heating and extraction time, concentration of reagent and interference from various ions were investigated. The stoichiometry of the extracted complex was determined by Job’s method of continuous variation, mole ratio method and slope ratio method. It was found that metal to ligand ratio was 1:2. The developed method has been successfully applied to the determination of platinum(IV) in pharmaceutical samples, catalyst and synthetic alloy sample.

Extractive Spectrophotometric Determination of Platinum in Cisplatin Injection, Alloys and Catalysts Assisted by 2-nitrobenzaldehydethiocarbohydrazone