Electrochemical Behavior of 4-(5’,6’,7’, 8’-Tetrahydro-naphthalene)-1-tetralone in Aprotic Media
Author(s) -
Kundan Singh Shekhawat,
Hemlata Sharma,
Samarth Bhargav,
Deepika Sharma
Publication year - 2013
Publication title -
chemical science transactions
Language(s) - English
Resource type - Journals
eISSN - 2278-3458
pISSN - 2278-3318
DOI - 10.7598/cst2013.574
Subject(s) - chemistry , tetralone , electrochemistry , horizontal scan rate , naphthalene , cyclic voltammetry , diffusion , cathodic protection , solvent , electrode , voltammetry , analytical chemistry (journal) , inorganic chemistry , organic chemistry , thermodynamics , physics
The electrochemical reduction of 4-(5',6',7',8'-tetrahydro-naphthalene)-1-tetralone was investigated in aprotic solvent dimethylsulphoxide at glassy carbon electrode (GCE) using the technique of cyclic voltammetry at room temperature. The reduction of tetralone carried out in acidic medium which is irreversible and involves transfer of two electrons. The intensity of cathodic peak current increases with increasing scan rate consistent with Randles-Sevcik equation. A linear behavior of peak current versus square root of scan rate indicates that the electrochemical reduction processes are diffusion controlled.
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