Synthesis and Properties of Polyurethane-Acrylate Top-Coating Agent
Author(s) -
Young-Joon Son,
Dong Jin Lee,
Jong Woo Bae,
Jeong Yong Lee
Publication year - 2015
Publication title -
elastomers and composites
Language(s) - English
Resource type - Journals
eISSN - 2288-7725
pISSN - 2092-9676
DOI - 10.7473/ec.2015.50.2.098
Subject(s) - polyurethane , acrylate , materials science , methacrylate , gloss (optics) , coating , polymer chemistry , methyl methacrylate , monomer , emulsion , butyl acrylate , ethyl acrylate , emulsion polymerization , chemical engineering , composite material , polymer , engineering
A series of polyurethane-acrylate hybrids were synthesized by 2-step emulsion polymerization of a variety of acrylate monomers such as 2-hydroxy ethyl methacrylate (HEMA), methyl methacrylate (MMA). Experiment was per- formed to improve stability and emulsibility of surface treatment agent, and it was found that the polyurethane-acrylate hybrids having an optimum composition (MMA : 20%, LA(EO)3-S : 3% and TDA-7 : 5%) was shown to be quite surface active in the solid contents. These results suggests that the optimal polyurethane-acrylate hybrids in this study have high potential as top coating agent, which may have high gloss and excellent properties.
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