Preparation and Characterizations of Polymethylmethacrylate (PMMA)/Acrylate Rubber (ACM) Blend for Light Diffuser Applications
Author(s) -
Byung Hwan Lee,
YoungWook Chang,
Hyung Mi Lim
Publication year - 2015
Publication title -
elastomers and composites
Language(s) - English
Resource type - Journals
eISSN - 2288-7725
pISSN - 2092-9676
DOI - 10.7473/ec.2015.50.1.049
Subject(s) - materials science , vulcanization , composite material , rheometer , natural rubber , ultimate tensile strength , extrusion , izod impact strength test , curing (chemistry) , rheology
Dynamically vulcanized PMMA/ACM (80 wt%/20 wt%) blend using DCP as a curing agent was prepared using internal mixer. The morphology, mechanical properties, optical properties, melt viscosity and die swell were characterized by using FE-SEM, tensile test, Izod impact test, dynamic mechanical analysis, ARES and capillary rheometer, respectively. The blends show a phase-separated morphology in which ACM are dispersed in PMMA matrix. Dynamically vulcanized blend exhibits higher mechanical properties, higher melt viscosity, and die swell as compared to simple blend. And, the dynamically vulcanized blend showed total transmittance of more than 75% and haze of higher than 90%, which enable it to find potential applications to fabricate an optical diffuser by extrusion process.
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