The Synthesis and X-ray Studies of 6-pyrrolidinyl-2-triazolyl Purine Arabinonucleoside | Zendy

Iriovosjolova | Zendy; Ērika Bizdēna | Zendy; Sergey Belyakov | Zendy; Māris Turks | Zendy

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The Synthesis and X-ray Studies of 6-pyrrolidinyl-2-triazolyl Purine Arabinonucleoside

Author(s) -

Iriovosjolova,

Ērika Bizdēna,

Sergey Belyakov,

Māris Turks

Publication year - 2013

Publication title -

material science and applied chemistry

Language(s) - English

Resource type - Journals

ISSN - 2255-8713

DOI - 10.7250/msac.2013.007

Subject(s) - moiety , pyranose , regioselectivity , chemistry , residue (chemistry) , nucleophile , pyrrolidine , derivative (finance) , stereochemistry , purine , organic chemistry , financial economics , economics , enzyme , catalysis

C(6)-Pyrrolidinyl derivative with triazolyl moiety at C(2)-position was obtained from 2,6-bis-triazolylpurine arabinonucleoside via C(6)-regioselective nucleophilic substituon of 1,2,3-triazolyl moiety with pyrrolidine. The obtained compound was studied by NMR, X-ray, UV/VIS and emission spectra. Pyranose form of arabinose residue and α-configuration of the obtained compound were unambiguously proven by NMR and X-ray studies.

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