Gas-Liquid Equilibrium Prediction of Ternary System (CO2-Ethanol-Water) at Moderate Pressures and Different Temperatures Using SRK-EOS
Author(s) -
Ghazi Faisal Najmuldeen,
Ghassan J. Hadi,
Arkan J. Hadi,
Iqbal Ahmed
Publication year - 2012
Publication title -
physical chemistry
Language(s) - English
Resource type - Journals
eISSN - 2167-7042
pISSN - 2167-7069
DOI - 10.5923/j.pc.20120201.01
Subject(s) - thermodynamics , ternary operation , mixing (physics) , bar (unit) , work (physics) , chemistry , equation of state , carbon dioxide , ternary numeral system , phase equilibrium , phase (matter) , physics , organic chemistry , quantum mechanics , meteorology , computer science , programming language
In this work, a thermodynamic model for the prediction of gas-liquid equilibrium at moderate pressures (up to 6 bar) and different temperatures (288-323 K) for the ternary system of carbon dioxide (1)-(2) mixture (ethanol-water) is established using Soave/Redlich/Kwong equation of state (SRK-EOS). Two different mixing rules were used to show the effect of the type of mixing rule. A comparison of experimental phase equilibrium data in the literature with the predicted results showed very good representation for one mixing rule and good for the other.
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