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Extraction of silica gel from Sorghum bicolour (L.) moench bagasse ash
Author(s) -
Mathew Mupa,
C B Hungwe,
Steffen Witzleben,
Courtie Mahamadi,
Netai MukaratirwaMuchanyereyi
Publication year - 2015
Publication title -
african journal of pure and applied chemistry
Language(s) - English
Resource type - Journals
ISSN - 1996-0840
DOI - 10.5897/ajpac2015.0603
Subject(s) - sodium hydroxide , silica gel , sodium silicate , bagasse , chemistry , sorghum , raw material , nuclear chemistry , leaching (pedology) , moisture , mineralogy , materials science , agronomy , pulp and paper industry , chromatography , soil water , composite material , organic chemistry , geology , soil science , engineering , biology
Sweet sorghum (Sorghum bicolor (L.) moench), a crop that is grown by subsistence farmers in Zimbabwe was used to extract silica gel in order to assess its possible use as a raw material for the production of silica-based products. The gel was prepared from sodium silicate extracted from sweet sorghum bagasse ash by sodium hydroxide leaching. Results show that maximum yield can be obtained at pH 5 and with 3 M sodium concentration. The silica gel prepared at optimum pH 5 had a bulk density of 0.5626 g/cm3 and anestimated porosity of 71.87%. Silica gel aged over 10 h had improved moisture adsorption properties. X-ray fluorescence (XRF) determinations show that the silica content in the ash is 40.1%. Characterization of sweet sorghum ash and silica gels produced at pH 5, 7 and 8.5 by Fourier Transform Infrared spectroscopy gave absorption bands similar to those reported by other researchers.Transmission electron micrographs show that silica prepared under optimum conditions is amorphous and consisted of irregular particles. Sweet sorghum proved to be a potential low cost raw material for the production of silica gel.   Key words: Silica gel, sweet sorghum, extraction, ash, bagasse, X-ray powder diffraction (XRD).

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