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Adsorption of heavy metal ions onto chitosan grafted cocoa husk char
Author(s) -
Adetutu Okoya Aderonke,
B. Akinyele Abimbola,
Eze S. Ifeanyi,
S. Amuda Omotayo,
S. Alayande Oluwagbemiga,
W. Makinde Oladotun
Publication year - 2014
Publication title -
african journal of pure and applied chemistry
Language(s) - English
Resource type - Journals
ISSN - 1996-0840
DOI - 10.5897/ajpac2014.0591
Subject(s) - freundlich equation , langmuir , husk , adsorption , chemistry , sorption , langmuir adsorption model , biosorption , nuclear chemistry , metal ions in aqueous solution , activated carbon , metal , organic chemistry , botany , biology
The use of chitosan-grafted cocoa husk char (CCH) and unmodified cocoa husk char (CH) as adsorbents for the removal of Cr6+ and Pb2+ were studied. The adsorption efficiencies were compared with that of the commercial activated carbon (GAC F-300). Energy Dispersive X-ray spectroscopy (EDS) was used to determine the elemental compositions of the adsorbents while Scanning Electron Microscope (SEM) was used for the surface texture and morphological characteristics of the cocoa husk. The study optimised metal ion concentration, adsorbent dosage, agitation time and adsorbent particle size for the removal of the metals from simulated wastewater using Atomic Absorption spectroscopy (AAS) and removal efficiencies were calculated. Langmuir and Freundlich models were employed to study the adsorption pattern. The equilibrium experimental data results of Pb2+ fitted well to Langmuir and Freundlich the two adsorption isotherms. The coefficient of correlation (R2) for both models falls within 0

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