Si Nanocrystals Embedded in a Silicon Oxynitride Matrix
Author(s) -
M. Ficcadenti,
N. Pinto,
L. Morresi,
G. Ferblantier,
M. Carrada,
A. Slaoui
Publication year - 2011
Publication title -
nanomaterials and nanotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.412
H-Index - 21
ISSN - 1847-9804
DOI - 10.5772/50954
Subject(s) - silicon oxynitride , materials science , silicon , plasma enhanced chemical vapor deposition , crystallization , nanocrystal , nanostructure , chemical vapor deposition , deposition (geology) , electron cyclotron resonance , chemical engineering , plasma , optoelectronics , analytical chemistry (journal) , nanotechnology , silicon nitride , chemistry , paleontology , physics , chromatography , quantum mechanics , sediment , engineering , biology
We investigated the morphological and structural change in silicon nanostructures embedded in the silicon oxynitride matrix. The study has been carried out on thin films thermally annealed at high temperature, after deposition at 400°C by Electron Cyclotron Resonance Plasma Enhanced Chemical Vapour Deposition (ECR‐ PECVD), under different deposition parameters. Our study evidenced the existence of a well defined threshold for the silicon content in the film (around 47%), to get Si nano‐crystallization in the silicon oxynitride matrix. Both Si nano‐crystals and Si nano‐columns have been observed by TEM analysis in two samples having a similar Si content but deposited under different conditions
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