Thermodynamics of Reactions Among Al2O3, CaO, SiO2 and Fe2O3 During Roasting Processes | Zendy

Zhongping Zhu | Zendy; Tao Jiang | Zendy; Guanghui Li | Zendy; Yufeng Guo | Zendy; Yongbin Yang | Zendy

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Thermodynamics of Reactions Among Al2O3, CaO, SiO2 and Fe2O3 During Roasting Processes

Author(s) -

Zhongping Zhu,

Tao Jiang,

Guanghui Li,

Yufeng Guo,

Yongbin Yang

Publication year - 2011

Publication title -

intech ebooks

Language(s) - English

Resource type - Book series

DOI - 10.5772/21545

Subject(s) - roasting , thermodynamics , chemistry , metallurgy , materials science , physics

The thermodynamic of the chemical reactions among Al2O3, CaO, SiO2 and Fe2O3 in the roasting processes was investigated in this chapter. The chemical reactions are classified into SiO2-Al2O3 system, Fe2O3-Al2O3 system, SiO2-Fe2O3 system, CaO-Al2O3 system, SiO2-CaO system, SiO2-calcium aluminates system, CaO-Fe2O3 system, Al2O3-calcium ferrites system and Al2O3-CaO-SiO2-Fe2O3 system. When the roasting temperature is over 1100K, 3Al2O3·2SiO2 is preferentially formed in SiO2-Al2O3 system; FeO·Al2O3 can be formed in Fe2O3-Al2O3 system; ferric oxide and SiO2 could not generate iron silicate; 12CaO·7Al2O3 is preferentially formed in CaO-Al2O3 system when one mole Al2O3 reacts with CaO; 2CaO·SiO2 is preferentially formed in SiO2-CaO system; except for CaO·2Al2O3 and CaO·Al2O3, the other calcium aluminates can transform into calcium silicate by reacting with SiO2 in SiO2-calcium aluminates system; 2CaO·Fe2O3 is preferentially formed in CaOFe2O3 system; alumina is unable to form 3CaO·Al2O3 with calcium ferrites(2CaO·Fe2O3 and CaO·Fe2O3), but able to form 12CaO·7Al2O3 with 2CaO·Fe2O3; when CaO, Fe2O3, Al2O3,SiO2 coexist, they are more likely to form ternary compound 2CaO·Al2O3·SiO2 and 4CaO·Al2O3·Fe2O3.

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