3-Formylindole-4-aminobenzoic Acid: A Potential Corrosion Inhibitor for Mild Steel and Copper in Hydrochloric Acid Media
Author(s) -
Aby Paul,
Joby Thomas Kakkassery,
Vinod P. Raphael,
K. S. Shaju
Publication year - 2012
Publication title -
isrn corrosion
Language(s) - English
Resource type - Journals
ISSN - 2090-8903
DOI - 10.5402/2012/842836
Subject(s) - hydrochloric acid , langmuir adsorption model , copper , dielectric spectroscopy , adsorption , corrosion , corrosion inhibitor , metal , chemistry , langmuir , electrochemistry , nuclear chemistry , inorganic chemistry , electrode , organic chemistry
The corrosion inhibition efficiencies of Schiff base 3-formylindole-4-aminobenzoic acid (3FI4ABA) on mild steel (MS) and copper in 1.0 M HCl solution have been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization studies. The results show that inhibition efficiencies on both metals increase with increasing the concentration of the inhibitor. 3FI4ABA exhibited comparatively good inhibition towards mild steel in HCl medium even at low concentrations. The adsorption of inhibitor on the surfaces of the corroding metal mild steel and copper obeys the Langmuir isotherm. Polarization studies revealed that 3FI4ABA acts as a mixed-type inhibitor. Thermodynamic parameters (, ) were calculated using the Langmuir adsorption isotherm.
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