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A novel catalytic system consisting of I 2 -SDS-H 2 O has been developed which cleaves 2,3-diaza-1,3-butadiene, 1-aza-1,3-butadienes, oximes and in presence of indoles in the medium uses the corresponding aldehyde products to produce bis(indolyl)alkanes  in situ . This one pot simple and mild dual catalytic system works in water at room temperature under neutral conditions.

isrn organic chemistry

<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:mrow><mml:msub><mml:mtext>I</mml:mtext><mml:mn mathvariant="bold">2</mml:mn></mml:msub></mml:mrow></mml:math>-SDS-<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M2"><mml:mrow><mml:msub><mml:mtext>H</mml:mtext><mml:mn mathvariant="bold">2</mml:mn></mml:msub><mml:mtext>O</mml:mtext></mml:mrow></mml:math> System: A highly Efficient Dual Catalytic Green System for Deprotection of Imines and <i>in Situ</i> …

I2-SDS-H2O System: A highly Efficient Dual Catalytic Green System for Deprotection of Imines and in Situ …