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Synthesis and Structural Properties of Copper(II), Nickel(II) and Cobalt(II) Complexes with 2,4-Furyliminobenzylacetophenone
Author(s) -
Jagvir Singh,
Prashant Singh
Publication year - 2012
Publication title -
isrn physical chemistry
Language(s) - English
Resource type - Journals
ISSN - 2090-7761
DOI - 10.5402/2012/504038
Subject(s) - cobalt , chemistry , nickel , copper , ligand (biochemistry) , metal , octahedral molecular geometry , schiff base , inorganic chemistry , microanalysis , nuclear chemistry , polymer chemistry , organic chemistry , biochemistry , receptor
The new Schiff base ligand (FIAS) 2,4-furyliminobenzylacetophenone has been synthesized with 4-aminoacetophenone and furane-2-carboxaldehyde by condensation in ethanol. Metal complexes of the ligand were prepared with chloride salts of copper(II), nickel(II) and cobalt(II) in ethanol. The ligand and its metal complexes have been characterized by microanalysis, magnetic susceptibility, FTIR, 1H and 13C NMR, mass spectrum, and UV-visible spectroscopy techniques. From these findings, it is suggested that metal ion coordinate by imines nitrogen and carboxylic oxygen atoms of FIAS to form octahedral geometry. All the newly compounds were tested antimicrobial activity against bacterial and fungal species.

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