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The influence of metal carbides, TiC, VC, ZrC, Mo2C, TaC, and WC, on the liquid-phase oxidation processes of 1-octene by molecular oxygen and tert-butyl hydroperoxide was investigated. It was established that vanadium carbide is the most active in the oxidation process of 1-octene by molecular oxygen as well as in the tert-butyl hydroperoxide unproductive decomposition process in the hydroperoxide oxidation reaction. It was shown that there is a correlation among the activities of metal carbides in these processes.

The Influence of Metal Carbides on the Oxidation Processes of 1-Octene by Molecular Oxygen and tert-Butyl Hydroperoxide