The Influence of Metal Carbides on the Oxidation Processes of 1-Octene by Molecular Oxygen and tert-Butyl Hydroperoxide | Zendy

Oksana Makota | Zendy; Lidiya Bulgakova | Zendy

Open Access

The Influence of Metal Carbides on the Oxidation Processes of 1-Octene by Molecular Oxygen and tert-Butyl Hydroperoxide

Author(s) -

Oksana Makota,

Lidiya Bulgakova

Publication year - 2012

Publication title -

isrn physical chemistry

Language(s) - English

Resource type - Journals

ISSN - 2090-7761

DOI - 10.5402/2012/135028

Subject(s) - carbide , vanadium , octene , metal , tert butyl hydroperoxide , oxygen , decomposition , 1 octene , materials science , chemistry , inorganic chemistry , metallurgy , catalysis , organic chemistry , ethylene

The influence of metal carbides, TiC, VC, ZrC, Mo2C, TaC, and WC, on the liquid-phase oxidation processes of 1-octene by molecular oxygen and tert-butyl hydroperoxide was investigated. It was established that vanadium carbide is the most active in the oxidation process of 1-octene by molecular oxygen as well as in the tert-butyl hydroperoxide unproductive decomposition process in the hydroperoxide oxidation reaction. It was shown that there is a correlation among the activities of metal carbides in these processes.

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