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Hollow hemispheric ZnO shells/cages are synthesized on graphite fiber via simple thermal evaporation process. The cage-like ZnO structures exhibit micron or submicron size and hollow hemispheric shape with polycrystalline shell made of the ZnO nanocrystals. Controlled time-sequenced growth experiment is conducted to interpret the growth process, which indicates that the growth mechanism of the hollow hemispheric ZnO shells/cages involves formation of Zn particles firstly, followed by oxidation of the outer surface of Zn droplets and meantime sublimation of the core Zn.

Controlled Synthesis of Hollow Hemispheric ZnO Shells/Cages on Graphite Fiber