Structural and Elastic Properties of Li-Ni Ferrite
Author(s) -
S.A. Mazen,
T.A. Elmosalami
Publication year - 2011
Publication title -
isrn condensed matter physics
Language(s) - English
Resource type - Journals
eISSN - 2090-7400
pISSN - 2090-7397
DOI - 10.5402/2011/820726
Subject(s) - lattice constant , debye model , materials science , spinel , bulk modulus , ferrite (magnet) , octahedron , diffraction , ion , elastic modulus , modulus , ceramic , nickel , analytical chemistry (journal) , crystallography , thermodynamics , chemistry , crystal structure , composite material , metallurgy , physics , optics , organic chemistry , chromatography
Li-Nickel ferrites with the chemical formula Li0.5−0.5NiFe2.5−0.5O4 (0.0≤≤1.0) have been prepared by the ceramic method. The spinel structure in homogenous state was realized by X-ray diffraction analysis. The lattice parameter has been determined for each composition and found to be nearly constant over the whole range of Ni concentration (= 0.83 nm ± 0.01). The cation distribution for each composition has been suggested. The experimental and theoretical lattice constants were found to be in good agreement with each other confirming the agreeability of the suggested cation distribution. The analysis of IR spectra indicates the presence of splitting in the absorption band due to the presence of small amounts of Fe2
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