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Effect of γ-Irradiation on the Dielectric and Conductivity Properties of Nano-Wollastonite
Author(s) -
Sandhya Kulkarni,
B.M. Nagabhushana,
Narsimha Parvatikar,
C. Shivakumara,
R. Damle
Publication year - 2011
Publication title -
isrn materials science
Language(s) - English
Resource type - Journals
eISSN - 2090-6099
pISSN - 2090-6080
DOI - 10.5402/2011/808560
Subject(s) - materials science , wollastonite , dielectric , nanocrystalline material , crystallite , ceramic , porosity , dissipation factor , conductivity , calcination , crystallization , composite material , mineralogy , dielectric loss , phase (matter) , analytical chemistry (journal) , chemical engineering , metallurgy , nanotechnology , chemistry , raw material , biochemistry , optoelectronics , organic chemistry , engineering , catalysis , chromatography
Nanocryst. porous CaSiO3 ceramic powders have been synthesized by a novel low-temp. initiated self-propagating, gas-producing soln. combustion method. Single phase β-CaSiO3 (Wollastonite) is formed by calcination at 900°C for 3h. The crystn. and phase formation temps. in this method are found to be lower compared to the powder obtained via solid state reaction method. The powder is characterized by powder XRD (X-Ray Diffraction), and crystallite sizes are evaluated using Scherrerf's formula as well as from TEM (Transmission Electron Microscopy). The Wollastonite powder is exposed to 60Co γ-radiation to accumulated doses of 1, 3, and 5 KGy and low-frequency (102-106 Hz) dielec. measurements are carried out before and after irradn. The dielec. cond. is estd. from the dielec. const. and loss tangent. Exposure to γ-radiation results in substantial modification in the properties of the ceramic powder due to changes in the porosity of the material. The correlation between dielec. and cond. properties is discussed in relation to porosity effect

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