Open AccessA Convenient Synthesis of Polycyclic γ-Lactams via Pauson-Khand Reaction
Author(s) -
Seok-Won Kim Kang
Publication year - 2009
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
eISSN - 1229-5949
pISSN - 0253-2964
DOI - 10.5012/bkcs.2009.30.3.691
Subject(s) - intramolecular force , ring (chemistry) , pauson–khand reaction , trimethylamine , yield (engineering) , chemistry , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , materials science , metallurgy
There still exists, however, a need for more efficient procedures for the synthesis of complex aza-polycyclic ring systems. Transition metal chemistry facilitates the combi-nation of unsaturated functional groups in ways that are difficult or impossible to accomplish using conventional synthetic methods. The Pauson-Khand reaction (PKR), the intramolecular cyclization of enynes mediated by Co
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