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In recent years, manychemical and biological methods for the synthesis ofoptically active epoxides, such as asymmetric epoxidation ofolefins, resolution of racemic epoxides and indirect chemicaltransformation, have been reported. However, the directasymmetric epoxidation of terminal olefins such as styreneanalogues catalyzed by salen and porphyrin ligands,

Facile Synthesis of Enantiopure 1,2-Diols and Terminal Epoxides from Chiral β-Hydroxy Sulfides