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Facile Synthesis of Enantiopure 1,2-Diols and Terminal Epoxides from Chiral β-Hydroxy Sulfides
Author(s) -
Byung-Tae Choi Cho
Publication year - 2003
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
eISSN - 1229-5949
pISSN - 0253-2964
DOI - 10.5012/bkcs.2003.24.7.1023
Subject(s) - enantiopure drug , terminal (telecommunication) , epoxide , chemistry , organic chemistry , stereochemistry , combinatorial chemistry , enantioselective synthesis , catalysis , computer science , telecommunications
In recent years, manychemical and biological methods for the synthesis ofoptically active epoxides, such as asymmetric epoxidation ofolefins, resolution of racemic epoxides and indirect chemicaltransformation, have been reported. However, the directasymmetric epoxidation of terminal olefins such as styreneanalogues catalyzed by salen and porphyrin ligands,

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