Spectrophotometric Determination of Copper(II) Using Diamine-Dioxime Derivative | Zendy

Khajadpai Thipyapong | Zendy; Chomchai Suksai | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Spectrophotometric Determination of Copper(II) Using Diamine-Dioxime Derivative

Author(s) -

Khajadpai Thipyapong,

Chomchai Suksai

Publication year - 2003

Publication title -

bulletin of the korean chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.237

H-Index - 59

eISSN - 1229-5949

pISSN - 0253-2964

DOI - 10.5012/bkcs.2003.24.12.1767

Subject(s) - diamine , copper , derivative (finance) , chemistry , diamine oxidase , polymer chemistry , organic chemistry , business , finance , enzyme

A simple, rapid and sensitive spectrophotometric method is herewith proposed for the determination of copper (II) by using diamine-dioxime ligand, meso-3,6,6,9-tetramethyl-4, 8-diazaundecane-2, 10-dione dioxime or meso-HexaMethyl Propylene Amine Oxime (meso-HMPAO). This method is based on the formation of a stable 1 : 1 red-pink complex between copper(II) and meso-HMPAO in aqueous solution Absorption measurements were carried at 497 nm, with a molar absorptivity value of 338 L mol-1 cm-1. Beer's law was obeyed over the concentration range of 0.5-370 μg mL - 1 with a Sandell's sensitivity value of 0.18 μg cm - 2 . The proposed method has been successfully applied for determination of copper (II) in foodstuffs and pharmaceutical samples. The results obtained from this method are comparable with those obtained AAS.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research